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Mixed-Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications covers all topics related to the theory and experimental results of mixed-valence systems, including the design, synthesis, and applications of mixed-valence compounds containing inorganic, organometallic and organic redox-active centers. The text also covers the recent advances in mixed-valence chemistry, including the development of new mixed-valence systems, transition of mixed valency, better understanding of the spectral characteristics of intervalence charge transfer, and controllable electron transfer related to molecular electronics. Strengthening the relationship of mixed-valence electron transfer and molecular electronics, Mixed-Valence Systems is of immense value to researchers and professionals working in the field of electron transfer, molecular electronics, and optoelectronics.
Introduction and Fundamentals of Mixed‐Valence Chemistry
Conceptual Understanding of Mixed‐Valence Compounds and Its Extension to General Stereoisomerism
Quantum Chemical Approaches to Treat Mixed‐Valence Systems Realistically for Delocalized and Localized Situations
Mixed Valency in Ligand‐Bridged Diruthenium Complexes
Electronic Communication in Mixed‐Valence (MV) Ethynyl, Butadiynediyl, and Polyynediyl Complexes of Iron, Ruthenium, and Other Late Transition Metals
Electron Transfer in Mixed‐Valence Ferrocenyl‐Functionalized Five‐ and Six‐Membered Heterocycles
Electronic Coupling and Electron Transfer in Mixed‐Valence Systems with Covalently Bonded Dimetal Units
Mixed‐Valence Electron Transfer of Cyanide‐Bridged Multimetallic Systems
Organic Mixed‐Valence Systems: Toward Fundamental Understanding of Charge/Spin Transfer Materials
Mixed‐Valence Complexes in Biological and Bio‐mimic Systems
Control of Electron Coupling and Electron Transfer Through Non‐covalent Interactions in Mixed‐Valence Systems
Stimulus‐Responsive Mixed‐Valence and Related Donor–Acceptor Systems
Mixed Valency in Extended Materials
Near‐Infrared Electrochromism Based on Intervalence Charge Transfer
Manipulation of Metal‐to‐Metal Charge Transfer Toward Switchable Functions